Duo MFA requires at least one "device" to be set up before you can use Duo Bypass Codes
You can use Mac Touch ID or Windows Hello on your non-Cisco computer to enroll into Duo. Once you are enrolled, please contact someone from the acquisition support team to get a Duo Bypass code
Bypass codes are only good for about 4 hours, so you will need to set up Duo with Windows Hello on your Cisco Cloud PC. You will only be able to use a PIN. Biometric and Face Recognition will not work on the Cloud PC
You should also obtain and configure a YubiKey or update your mobile device to run Duo Mobile push. There are some Cisco resources that cannot use Windows Hello